tank contains 200 litres = 1/5 of tank .....we are told this Tank will be full when it is 5/5 full ....that means is needs 4/5 to fill it. 4/5 of tank = 4 x 1/5 = 4 x 200 = 800 litres needed to fill tank.
If question had said .... A tank of capacity 200 litres is 1/5 full. How much is reqd to fill the tank..... Then ....... Tank full = 200 litres. Now contains 1/5 of capacity..... 1/5 of 200 = 40 litres